Adsorptive desulfurization and denitrogenation of model fuel by mesoporous adsorbents (MSU-S and CoO-MSU-S)

Adsorption of heterocyclic sulfur- and nitrogen-containing compounds by mesostructure adsorbent (MSU-S) and its modified form with cobalt oxide is studied using model fuel. The results of characteristic tests (XRD, N₂ adsorption–desorption, FTIR, and SEM) indicate that CoO impregnation causes a negative impact on mesoporous structure, crystalline phase, and particle shape along with a positive effect on surface ion exchange. CoO modification increased the adsorption loadings of DBT and BT to about 33.6% and 45.7%, respectively. For nitrogen compounds adsorption with the model fuel, adsorption loadings of quinoline and carbazole increase by 6.7% and 8.6%, respectively. Data fitting for carbazole, DBT, and BT is achieved better by the Langmuir model than the Freundlich model, and the data of quinoline fitted very well to the Freundlich model for CoO-MSU-S.     

Physical and Morphological Properties of Combined Treated Wood Polymer Composites by Maleic Anhydride and Methyl Methacrylate

Wood polymer composites were prepared by consecutive impregnation with maleic anhydride (MAN) and methyl methacrylate (MMA). Samples impregnated with MAN alone, were heated at 120°C and 150°C for 4 and 8 h. Based on the Fourier transform infrared (FT-IR) analysis and soaking-drying test results, treatment with MAN at 150°C for 4 h resulted in formation of stable crosslinks. In the second stage, MMA was used for in situ polymerization within MAN-treated wood. Field emission scanning electron microscopy observation and FT-IR analysis indicated that MMA copolymerized with MAN, and the resultant polymer filled up the lumen and is also grafted on to the cell wall. Improvement of water repellency and dimensional stability were observed in the treated samples, particularly in combined treated samples. The MAN/MMA treatment improved interaction between polymer and wood.     

Assessment of information technology effects on management of supply chain based on fuzzy logic in Iran tail industries

Evolutions rooted in technology in market arena, business, and demands reforms in supply chain and consequently more demands for created value by end user are among factors causing reforms on management of supply chain. Integrity of supply chain activities and utilized technologies is an essential factor to survive competitions in the market. Organizations, therefore, need to adopt policies to coordinate themselves with new arena in market and electronic commerce. Despite bad news from Iran tail industries about unplanned production, the industry is still in growing path. In addition to easy access to mineral resources and low-energy costs, which have made it quite reasonable to invest in the industry, state tariff policies for imported tail products have made new investment chances in the industry. As a result, Iran recently won a position among five leading counties in world tail industry. However, knowing about high profit margin in tail industries, many countries have stepped into the market and through producing high-quality products have intensified competition in the market. This study tries to identify and assess IT indexes in Iran tail industry’s supply chain and hopes to take a step forward to gain better market position in international market by prioritizing the indexes using fuzzy logic.     

Optimising the ice cream formulation using basil seed gum (Ocimum basilicum L.) as a novel stabiliser to deliver improved processing quality

Mixture design was used to determine the optimum ratio as well as concentration of basil seed gum (BSG), guar gum (GG) and carboxymethyl cellulose (CMC) in the formulation of ice cream stabilisers. Predicted equations and contour plots of physicochemical responses were also generated. Generally, increasing the ratio of BSG in gums mixture increased the apparent viscosity of ice cream mixes and decreased the melting rate. Increasing the proportion of GG at concentration of 0.35% enhanced overrun of samples. High ratios of BSG at concentration of 0.35% and CMC at concentration of 0.15% increased the fat destabilisation in ice creams. Combination of 84.31% BSG and 15.69% CMC at concentration of 0.35% proposed as optimum formulation which verified in practice. Introducing BSG as a novel source of stabiliser could be promising as alternative and improve the quality and diversity of ice cream and related products.     

Shock-Wave Attenuation and Energy-Dissipation Potential of Granular Materials

The propagation of uniaxial-stress planar shocks in granular materials is analyzed using a conventional shock-physics approach. Within this approach, both compression shocks and decompression waves are treated as (stress, specific volume, particle velocity, mass-based internal energy density, temperature, and mass-based entropy density) propagating discontinuities. In addition, the granular material is considered as being a continuum (i.e., no mesoscale features like grains, voids, and their agglomerates are considered). However, while the granular material is treated as a (smeared-out) continuum, it is recognized that it contains a solid constituent (parent matter), and that the structurodynamic properties (i.e., Equations of State (EOS) and Hugoniot relations) of the granular material are related to its parent matter. Three characteristic shock loading regimes of granular material are considered and, in each case, an analysis is carried out to elucidate shock attenuation and energy dissipation processes. In addition, an attempt is made to identify a metric (a combination of the material parameters) which quantifies the intrinsic ability of a granular material to attenuate a shock and dissipate the energy carried by the shock. Toward that end, the response of a typical granular material to a flat-topped compressive stress pulse is analyzed in each of the three shock loading regimes.     

Seismic microzonation and building vulnerability assessment based on site characteristic and geotechnical parameters by use of Fuzzy-AHP model (a case study for Kermanshah city)

ABSTRACT

On 12th November 2017, an earthquake with a magnitude of 7.3 Richter scale in the town of Sarpol-e Zahab took place that caused lots of human casualties and devastation. After the incident, issues related to the probability of an earthquake with equal intensity and extents of similar building destruction were raised in Kermanshah city. Therefore, a seismic microzonation map of Kermanshah city has been prepared based on the geotechnical, geological, and geophysical data, and the data were analysed using Fuzzy analytic hierarchy process (AHP). In the next step, the vulnerability analysis of city buildings was carried out based on the ground-shaking map, vulnerability curves, and statistical data regarding the buildings. The results of the vulnerability rate of residential buildings indicate that 80% of residential buildings would be exposed to vulnerability from low to moderate. However, other buildings would suffer 2% fully destruction (D1), 7% very high destruction (D2) and 11% high destruction (D3), respectively. Finally, according to the obtained results, the proposed model is verified with the help of the data and observations from the Sarpol-e Zahab earthquake, which reveals that the model is in good agreement with the actual earthquake data.     

Role of morphology in electrochemical hydrogen storage using binary DyFeO3-ZnO nanocomposites as electrode materials

Hydrogen storage technology is one of the most challenging issues due to the increasing demand for fossil fuel replacement and the reduction of greenhouse gas emissions. In the current paper, the main aim is one-step and eco-friendly preparation of DyFeO₃-ZnO nanocomposites using Barberry fruit extract as natural precursor (with the role of both fuel and capping agent) to compare with various conventional carboxylic acids. To further examine, the effect of different parameters like calcination temperature and the type of the chelating agent was scrutinized to acquire optimum shape, structure, morphology and size of the obtained products. This is the first effort on the investigation of the hydrogen storage capacity of DyFeO₃-ZnO nanocomposites in terms of role of morphology. The electrochemical hydrogen storage capacity of obtained DyFeO₃-ZnO nanocomposites was studied mediated by chronopotentiometry charge-discharge methods in KOH medium. The synthesis of nanocomposites in the presence of chemical or natural capping agent (carboxylic acids or Barberry fruit extract) led to different morphologies which affects to the electrochemical performance. As a result, the electrode which is provided by plate-like DyFeO₃-ZnO nanocomposites performed 600.11 mAh/g discharge capacity compared with other samples. Based on the obtained results, DyFeO₃-ZnO nanocomposites can be promising compounds to improve the electrochemical performance of hydrogen storage.     

Enhancing the Tribological Behavior of Lubricating Oil by Adding TiO2, Graphene,and TiO2/Graphene Nanoparticles

This article investigates the tribological behavior of nanoparticles (NPs) of titanium dioxide anatase TiO₂ (A), graphene, and TiO₂ (A) + graphene added to the pure base oil group ΙΙ (PBO-GΙΙ). The morphology of these two nanostructures of TiO₂ (A) and graphene was characterized by transmission electron microscopy (TEM). Oleic acid (OA) was blended as a surfactant into the formulation to help stabilize the NPs in the lubricant oil. A four-ball test rig was used to determine the tribological performance of six different samples, and an image acquisition system was used to examine and measure the wear scar diameter of the stationary balls. Field emission–scanning electron microscopy (FE-SEM) was used to examine the wear morphology. Energy-dispersive X-ray spectroscopy (EDX), element mapping, and Raman spectroscopy were employed to confirm the presence of (TiO₂ (A) + graphene) and the formation of a tribolayer/film on the mating surfaces. Moreover, a 3D optical surface texture analyzer was utilized to investigate the scar topography and tribological performance. The experiments proved that adding (0.4?wt% TiO₂ (A) + 0.2?wt% graphene) to the PBO-GΙΙ optimized its tribological behavior. These excellent results can be attributed to the dual additive effect and the formation of a tribofilm of NPs during sliding motion. Furthermore, the average reductions in the coefficient of friction (COF), wear scar diameter (WSD), and specific wear rate (SWR) were 38.83, 36.78, and 15.78%, respectively, for (0.4?wt% TiO₂ (A) + 0.2?wt% graphene) nanolubricant compared to plain PBO-GΙΙ lubricant.     

Lighting preferences in office spaces concerning the indoor thermal environment

The accurate prediction of the visual comfort zone in an indoor environment is difficult as it depends on many parameters. This is especially the case for large compact urban areas in which the density and shadow from neighboring buildings can limit the accessible daylighting in indoor spaces. This paper investigates the satisfaction range for illuminance regarding indoor air temperature in office buildings and the significant parameters affecting this range in six office buildings in Tehran, Iran. Lighting comfort has been evaluated by a subjective survey (509 total responses) and field measurement. The questionnaires were filled out in 146 and 109 rooms in summer and winter, respectively. The results show that the illuminance should not be less than 550 lx, while illuminance between 600 and 650 lx provides the highest satisfaction level. The satisfaction with lighting level is affected by individual parameters such as age, type of activity, and environmental parameters such as window orientation, external obscurations, and season. A relationship was observed between lighting level satisfaction and thermal condition acceptance, and the overall comfort depends more on thermal conditions than the lighting level.     

Pure Hydrogen and Propylene Coproduction in Catalytic Membrane Reactor-Assisted Propane Dehydrogenation

Propane dehydrogenation on a commercial Pt-Sn/Al₂O₃ catalyst in a Pd-Ag membrane reactor is considered. A mathematical model is developed to evaluate the performance of the catalytic membrane reactor for the process of propane dehydrogenation. Design and operating conditions are systematically evaluated for key performance metrics such as propane conversion, propylene selectivity, hydrogen selectivity, and hydrogen recovery under different operating conditions. The results confirm that the high performance of the membrane reactor is related to the continuous removal of hydrogen from the reaction zone to shift the reaction equilibrium towards the formation of more propylene and hydrogen.